Demarlon Ware was arrested Thursday by Ouachita Parish sheriff's deputies.
Ware was wanted in connection with a January 2010 home invasion that left another suspect dead.
Police say, ware, George Collier and Ervin Ausberry were attempting to break into a house on south 9th street in West Monroe.
The men got into a fight with the home owner and Ausberry was shot and killed.
Collier was arrested back in 2010 and charged with second degree murder.
Ware is charged with second degree murder, attempted robbery and burglary.